Gamma irradiation was used to prepare nanocomposite hydrogels composed of polyacrylamide (PAM) and chitosan nanoparticles (CS-NPs). The hydrogels were investigated by FT-IR spectroscopic analysis, thermogravimetric analysis (TGA) and the measurements of swelling in water. The metal sorption and kinetics for Cu+2, Pb+2 and Fe+3 metal ions was investigated. The results of TGA analysis showed that the PAM/CS-NPs hydrogels had lower thermal stability than PAM hydrogel. It was found that PAM and PAM/CS-NPs hydrogels reached the equilibrium swelling in water at 4 hours. However, PAM/CS-NPs hydrogels displayed higher swelling in water than PAM hydrogel. The metal sorption study showed that PAM/CS hydrogels shad high affinity and selectivity for the metal ions according to the order: of Cu+2 > Pb+2 > Fe+3. On the other hand, the sorption by the hydrogel networks is controlled by applying Fick's law.
khalil, S., khafaga, M., & El-naggar, A. (2024). Characterization and Metal Sorption of PolyAcrylamide /Chitosan Nanocomposite Hydrogel Synsisyezed by Gamma Irradiation. Egyptian Journal of Chemistry, 67(3), 107-115. doi: 10.21608/ejchem.2023.219201.8247
MLA
salwa abdel-sadek khalil; mervat rabie khafaga; abdel-wahab khalil El-naggar. "Characterization and Metal Sorption of PolyAcrylamide /Chitosan Nanocomposite Hydrogel Synsisyezed by Gamma Irradiation". Egyptian Journal of Chemistry, 67, 3, 2024, 107-115. doi: 10.21608/ejchem.2023.219201.8247
HARVARD
khalil, S., khafaga, M., El-naggar, A. (2024). 'Characterization and Metal Sorption of PolyAcrylamide /Chitosan Nanocomposite Hydrogel Synsisyezed by Gamma Irradiation', Egyptian Journal of Chemistry, 67(3), pp. 107-115. doi: 10.21608/ejchem.2023.219201.8247
VANCOUVER
khalil, S., khafaga, M., El-naggar, A. Characterization and Metal Sorption of PolyAcrylamide /Chitosan Nanocomposite Hydrogel Synsisyezed by Gamma Irradiation. Egyptian Journal of Chemistry, 2024; 67(3): 107-115. doi: 10.21608/ejchem.2023.219201.8247