The manganese based MOF (Mn(BDC)(H2O)2); was successfully synthesized via a microwave method. The features of the Mn-MOF was evaluated by XRD, TGA, N2 adsorption-desorption at -196ºC, FTIR and SEM. The elimination of heavy metal ions from aqueous solution via Mn-MOF was described by batch adsorption tests including kinetic and thermodynamic models. Mn-MOF exhibited a very high adsorption efficiency towards Cd(II), Pb(II) and Hg(II) from aqueous solution (81.89%, 71.19% and 65.19% respectively). Adsorption kinetics data evidenced that heavy metal ions adsorption isotherms appropriated the Langmuir model and conform the pseudo-second-order kinetic equation. Successfully, the Mn-MOF was reused illustrative in the first run, the adsorbed amounts for (Cd(II), pb(II) and Hg(II)) were (80.2%, 69.6% and 64%) after fifth run became (68%, 54.74% and 50.98% respectively) which is elucidating its potential for heavy metal ions decontamination application.
Abd El Salam, H., & Sharara, T. (2019). A Novel Microwave Synthesis of Manganese Based MOF for Adsorptive of Cd(II), Pb(II) and Hg(II) Ions from Aqua Medium. Egyptian Journal of Chemistry, 62(5), 837-851. doi: 10.21608/ejchem.2019.6524.1550
MLA
Howaida Abd El Salam; Tamer Sharara. "A Novel Microwave Synthesis of Manganese Based MOF for Adsorptive of Cd(II), Pb(II) and Hg(II) Ions from Aqua Medium". Egyptian Journal of Chemistry, 62, 5, 2019, 837-851. doi: 10.21608/ejchem.2019.6524.1550
HARVARD
Abd El Salam, H., Sharara, T. (2019). 'A Novel Microwave Synthesis of Manganese Based MOF for Adsorptive of Cd(II), Pb(II) and Hg(II) Ions from Aqua Medium', Egyptian Journal of Chemistry, 62(5), pp. 837-851. doi: 10.21608/ejchem.2019.6524.1550
VANCOUVER
Abd El Salam, H., Sharara, T. A Novel Microwave Synthesis of Manganese Based MOF for Adsorptive of Cd(II), Pb(II) and Hg(II) Ions from Aqua Medium. Egyptian Journal of Chemistry, 2019; 62(5): 837-851. doi: 10.21608/ejchem.2019.6524.1550
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