• Home
  • Journal Info
    • About Journal
    • Aims and Scope
    • Editorial Board
    • Publication Ethics
    • Indexing and Abstracting
    • Related Links
    • FAQ
    • Peer Review Process
    • News
  • Guide for Authors
    • Author Template
  • Submit Manuscript
  • Browse
    • Current Issue
    • By Issue
    • By Author
    • By Subject
    • Author Index
    • Keyword Index
  • Contact Us
 
  • Login
  • Register
Home Articles List Article Information
  • Save Records
  • |
  • Printable Version
  • |
  • Recommend
  • |
  • How to cite Export to
    RIS EndNote BibTeX APA MLA Harvard Vancouver
  • |
  • Share Share
    CiteULike Mendeley Facebook Google LinkedIn Twitter
Egyptian Journal of Chemistry
arrow Articles in Press
arrow Current Issue
Journal Archive
Volume Volume 64 (2021)
Issue Issue 3
Issue Issue 2
Issue Issue 1
Volume Volume 63 (2020)
Volume Volume 62 (2019)
Volume Volume 61 (2018)
Volume Volume 60 (2017)
Volume Volume 59 (2016)
Volume Volume 58 (2015)
Volume Volume 57 (2014)
Volume Volume 56 (2013)
Volume Volume 55 (2012)
Volume Volume 54 (2011)
Volume Volume 53 (2010)
Hameed, G., Wadday, F., Farhan, M., Hussain, S. (2021). Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. Egyptian Journal of Chemistry, 64(3), 1333-1345. doi: 10.21608/ejchem.2020.49716.3034
Ghusoon Faidhi Hameed; Fawzi Wadday; Murtadha Abd Ali Farhan; Sahar Aqeel Hussain. "Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor". Egyptian Journal of Chemistry, 64, 3, 2021, 1333-1345. doi: 10.21608/ejchem.2020.49716.3034
Hameed, G., Wadday, F., Farhan, M., Hussain, S. (2021). 'Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor', Egyptian Journal of Chemistry, 64(3), pp. 1333-1345. doi: 10.21608/ejchem.2020.49716.3034
Hameed, G., Wadday, F., Farhan, M., Hussain, S. Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor. Egyptian Journal of Chemistry, 2021; 64(3): 1333-1345. doi: 10.21608/ejchem.2020.49716.3034

Synthesis, Spectroscopic characterization and bactericidal valuation of some metal (II) complexes with new Tridentate Heterocyclic Azo Ligand Type (NNO) Donor

Article 23, Volume 64, Issue 3, March 2021, Page 1333-1345  XML PDF (1.25 MB)
Document Type: Original Article
DOI: 10.21608/ejchem.2020.49716.3034
Authors
Ghusoon Faidhi Hameedorcid 1; Fawzi Wadday email orcid 2; Murtadha Abd Ali Farhan1; Sahar Aqeel Hussainorcid 3
1Department of Chemistry, College of Education, University of Al-Qadisiyah, Qadisiyah, Iraq
2Chemistry Department, Science of College, Kufa of University, Al-Najaf, Iraq
3Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Kufa University, Al-Najaf-Iraq
Receive Date: 20 November 2020,  Revise Date: 12 December 2020,  Accept Date: 20 December 2020 
Abstract
Abstract
In this article, a synthesized ligand [(1-phenyl-2-pyrazolin-5-one) azo (6-bromo-2-hydroxynaphthalen-1-yl)] has employed for preparing three new complexes of Co(II), Ni(II) and Cu(II). The new azo ligand (PABH) has analyzed by Micro Elemental Analysis (CHNO), UV-visible, Fourier Transform infrared (FTIR) approaches, 1H,13C-NMR spectroscopy and mass spectroscopy. The consequence has specified that the ligand was represented as N,N,O-tridentate. The preparing of complexes has accomplished after fixing the finest concentration and pH values. UV-Vis spectra of these complexes solutions have been examined for a range of pH (5-9) and concentration (1×10-4 - 5×10-4) Molar that comply with Lambert-Beers law. A stoichiometry of the complexes has comprehended in relation to mole ratio which has investigated from a spectroscopic technique. The ratio of metal: ligand was achieved with (1:2) for all complexes. The metal ions complexes were characterized by FTIR, UV-Visible, molar conductance, atomic absorption, magnetic susceptibility and elemental analysis CHNO techniques. From the results of physico-chemical and spectral techniques, octahedral geometry has been proposed for these metal complexes. All these compounds were evaluated against two kinds of human pathogenic bacteria such as Staphylococcus aureus (Gram Positive) and Escherichia coli (Gram negative).
Keywords
Spectral studies; Complexes; Azo; Antimicrobial activity; Mass spectroscopy
Main Subjects
Inorganic chemistry
Statistics
Article View: 113
PDF Download: 49
Home | Glossary | News | Aims and Scope | Sitemap
Top Top

Journal Management System. Designed by NotionWave.