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Egyptian Journal of Chemistry
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Volume Volume 64 (2021)
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Amer, I. (2021). Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III). Egyptian Journal of Chemistry, 64(3), 1441-1446. doi: 10.21608/ejchem.2020.22459.2338
Iqab Adel Amer. "Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)". Egyptian Journal of Chemistry, 64, 3, 2021, 1441-1446. doi: 10.21608/ejchem.2020.22459.2338
Amer, I. (2021). 'Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)', Egyptian Journal of Chemistry, 64(3), pp. 1441-1446. doi: 10.21608/ejchem.2020.22459.2338
Amer, I. Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III). Egyptian Journal of Chemistry, 2021; 64(3): 1441-1446. doi: 10.21608/ejchem.2020.22459.2338

Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)

Article 33, Volume 64, Issue 3, March 2021, Page 1441-1446  XML PDF (510.64 K)
Document Type: Original Article
DOI: 10.21608/ejchem.2020.22459.2338
Author
Iqab Adel Amer email
Department of chemistry, Arab American University, Palestine
Receive Date: 15 January 2020,  Revise Date: 02 May 2020,  Accept Date: 16 December 2020 
Abstract
The reaction of 2-methylindole with hexacyanoferrate(III) in alkaline media to produce the corresponding 2-methylindolin-3-one has been studied at constant temperature and ionic strength. The reaction followed first order kinetics with respect to [2-methylindole], [OH-] and [Fe(CN)63-]. The effects of added electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. On the basis of experimental observations, a probable reaction mechanism has been proposed.
Keywords
2-methylindole; hexacyanoferrate(III); 2-methylindolin-3-one; kinetics and oxidation
Main Subjects
Physical chemistry
Statistics
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PDF Download: 11
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