Extraction of Aromatic Hydrocarbons from Light Petroleum Fractions with Lactam Solvent

Mawgoud, Hussien Abed El; Elmelawy, Mamdouh Saad; Hanafy, Samia Abbas; Badr, Magd M

doi:10.21608/ejchem.2024.291035.9747

Extraction of Aromatic Hydrocarbons from Light Petroleum Fractions with Lactam Solvent

Document Type : Review Articles

Authors

¹ Egyptian petroleum research institute

² Refining Department, Egyptian Petroleum Research Institute

³ Egyptian Petroleum Research Institute(EPRI)

⁴ 1-Ahmed Elzomar Street Elzohour Region

10.21608/ejchem.2024.291035.9747

Abstract

Abstract
The investigation and modeling of phase equilibrium in the extraction of aromatics from naphtha reformate using N-(β-cyanoethyl)-ε-caprolactam (NCECL) and water were conducted using the ASPEN HYSYS Program. The extraction process was studied at various temperatures (50, 70, 95, 110, and 125°C) and different proportions of water in the NCECL solvent (2%, 5%, and 8% by weight). The solvent-to-feed ratio was maintained at 2:1, and the concentration of aromatics in the feed remained constant at 42.71% by weight. Experimental results were compared to predictions made using the UNIFAC method. Successful predictions were made for the aromatic extraction capacity from reformation, processing index, solvent power, and solvent selectivity. The impact of water-content and temperature on selectivity, solubility, and distribution coefficient was investigated, and the equilibrium data was used to calculate the values of the distribution coefficient and selectivity. A low root mean square deviation value was obtained, and the experimental and calculated extract yields were determined under the best operating conditions, considering the specified temperature and water content. The optimal operating conditions were found to be a temperature of 50°C and a water content of 2%, resulting in extract yields of 52.77% and 56.80% for the experimental and calculated values, respectively.

Keywords