Synthesis of Some New α, β-Unsaturated Carbonyl Compounds, Thiophene, Imine and Coumarin Derivatives Containing Hydrazide-Hydrazone Moiety

Document Type : Original Article

Authors

Department of Chemistry, College of Science, University of Mosul, Mosul, IRAQ.

Abstract

Abstract

A series of new α,β-unsaturated carbonyl compounds , thiophene, imine and coumarin derivatives were synthesized from reaction of hydrazide-hydrazone derivative with different reagents (substituted aromatic ketone, cyclopentanone, cycloheptanone, tetralone, malononitrile, 2-hydroxy-1-benzaldehyde and 2-hydroxy-1-naphthaldehyde) using different conditions. Hydrazide-hydrazone derivative was prepared by the reaction of piperonal with 2-cyanoacetohydrazide under reflux in ethanol. On the basis of their spectral information, the structures of the newly synthesized chemical derivatives were determined.

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