NOVEL soluble peripherally tetrasubstituted metal-phthalocyanines: 2(3),9 10), ……16 (17),23(24) – tetrakis - 2'-(4-hexafluoroisopropylidene-phthalic acid)-phthalocyanines [(R4Pc)M] where R= (4,4`-(hexafluoroisopropylidene) bis-phthalic acid and M= Co(II), Ni(II) and Cu(II) 2-4, have been prepared. Additionally, the soluble hexafluoroisopropylidene bridged high molecular weight phthalocyanines 5-7 were obtained by controlling the reaction conditions such as molar ratio of the reactant, reaction time and temperature. Structural and spectral investigations (FAB-MS, MALDI-TOF-MS, 1H-NMR, atomic absorption spectroscopy (AAS), elemental analysis, UV/Vis, FTIR, TGA, and GPC) of the prepared phthalocyanines revealed some interesting observations.
(2010). Synthesis of Highly Soluble Fluoro Containing Metal -phthalocyanines and (Hexafluoroisopropylidene) -bridged Metal-phthalocyanine Polymers. Egyptian Journal of Chemistry, 53(6), 939-954. doi: 10.21608/ejchem.2010.1272
MLA
. "Synthesis of Highly Soluble Fluoro Containing Metal -phthalocyanines and (Hexafluoroisopropylidene) -bridged Metal-phthalocyanine Polymers", Egyptian Journal of Chemistry, 53, 6, 2010, 939-954. doi: 10.21608/ejchem.2010.1272
HARVARD
(2010). 'Synthesis of Highly Soluble Fluoro Containing Metal -phthalocyanines and (Hexafluoroisopropylidene) -bridged Metal-phthalocyanine Polymers', Egyptian Journal of Chemistry, 53(6), pp. 939-954. doi: 10.21608/ejchem.2010.1272
VANCOUVER
Synthesis of Highly Soluble Fluoro Containing Metal -phthalocyanines and (Hexafluoroisopropylidene) -bridged Metal-phthalocyanine Polymers. Egyptian Journal of Chemistry, 2010; 53(6): 939-954. doi: 10.21608/ejchem.2010.1272
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