TRIPHENYLPHOSPHINE (1) reacts with 2,6-bis(4-azido-benzylidene)-4-methylcyclohexanone (4) to give the respective triphenylphosphinylidenetriaz-1-enyl (5a) and triphenylphosphinylidene- amino (5b). Moreover, reaction of aryl azide (4) with trisdimethy-laminophosphine (2) in refluxing toluene afforded the new products (6a, b). On the other hand, phosphorus ylides (3a-d) react with azidobenz-ylidene (4) to give the corresponding 1,5-disubstituted-1,2,3-triazoles (7a-d) and triphenylphosphine oxide. Possible reaction mechanisms are considered and the structural assignments are based on compatible analytical and spectroscopic results.
(2010). Reaction of 2,6-Bis(4-azidobenzylidene)-4-methyl-cyclohexanone with Organophosphorus Reagents. Synthesis of Some Benzylidene-1, 2, 3-triazole Derivatives. Egyptian Journal of Chemistry, 53(2), 203-214. doi: 10.21608/ejchem.2010.1212
MLA
. "Reaction of 2,6-Bis(4-azidobenzylidene)-4-methyl-cyclohexanone with Organophosphorus Reagents. Synthesis of Some Benzylidene-1, 2, 3-triazole Derivatives", Egyptian Journal of Chemistry, 53, 2, 2010, 203-214. doi: 10.21608/ejchem.2010.1212
HARVARD
(2010). 'Reaction of 2,6-Bis(4-azidobenzylidene)-4-methyl-cyclohexanone with Organophosphorus Reagents. Synthesis of Some Benzylidene-1, 2, 3-triazole Derivatives', Egyptian Journal of Chemistry, 53(2), pp. 203-214. doi: 10.21608/ejchem.2010.1212
VANCOUVER
Reaction of 2,6-Bis(4-azidobenzylidene)-4-methyl-cyclohexanone with Organophosphorus Reagents. Synthesis of Some Benzylidene-1, 2, 3-triazole Derivatives. Egyptian Journal of Chemistry, 2010; 53(2): 203-214. doi: 10.21608/ejchem.2010.1212
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